Disordered Gd6UO12-δ with the cation antisite defects prepared by a combined ...

@article{59001,
   author = {Darin, G. and Imakuma, K. and Santiago, R.T. and Da Silva, K.L. and Cótica, L.F. and Fabián, M. and Valíček, Jan and Hahnd, H. and Šepeľák, Vladimír},
   article_location = {AMSTERDAM, NETHERLANDS},
   article_number = {June 2021},
   keywords = {Gd6UO12; Cation antisite disorder; Oxygen deficiency; Mechanochemistry; Rietveld refinement},
   language = {eng},
   issn = {0022-3115},
   journal = {Journal of Nuclear Materials},
   title = {Disordered Gd6UO12-δ with the cation antisite defects prepared by a combined mechanochemical−thermal method},
   url = {https://www.sciencedirect.com/science/article/abs/pii/S0022311521001185?via%3Dihub},
   volume = {549/2021},
   year = {2021}
}

TY  - JOUR
ID  - 59001
AU  - Darin, G. - Imakuma, K. - Santiago, R.T. - Da Silva, K.L. - Cótica, L.F. - Fabián, M. - Valíček, Jan - Hahnd, H. - Šepeľák, Vladimír
PY  - 2021
TI  - Disordered Gd6UO12-δ with the cation antisite defects prepared by a combined mechanochemical−thermal method
JF  - Journal of Nuclear Materials
VL  - 549/2021
IS  - June 2021
SP  - 152895-152900
EP  - 152895-152900
PB  - ELSEVIER
SN  - 00223115
KW  - Gd6UO12
KW  - Cation antisite disorder
KW  - Oxygen deficiency
KW  - Mechanochemistry
KW  - Rietveld refinement
UR  - https://www.sciencedirect.com/science/article/abs/pii/S0022311521001185?via%3Dihub
N2  - The synthesis of the rhombohedral Gd6UO12-δ is reported via mechanochemical processing of stoichiomet ric Gd2O3/UO2 mixtures and their subsequent annealing. Rietveld refinement of XRD data reveals that the as-prepared material exhibits a remarkable degree of cation antisite disorder and oxygen deficiency. The simulations of intensities of the selected XRD superlattice reflections are performed for limiting states of Gd6UO12-δ with its most extreme degrees of the cation antisite disorder. On the basis of the estimated bond lengths it can be stated that distorted geometry of structural units in the material is a consequence of its relatively large oxygen deficiency.
ER  - 

DARIN, G., K. IMAKUMA, R.T. SANTIAGO, K.L. DA SILVA, L.F. CÓTICA, M. FABIÁN, Jan VALÍČEK, H. HAHND and Vladimír ŠEPEĽÁK. Disordered Gd6UO12-δ with the cation antisite defects prepared by a combined mechanochemical−thermal method. Online. \textit{Journal of Nuclear Materials}. AMSTERDAM, NETHERLANDS: ELSEVIER, 2021, 549/2021, June 2021, p.~152895-152900. ISSN~0022-3115. [citováno 2024-04-24]