More then 20 years the chemistry of surface water has been observed within GEOMON project in the Zdíkov region in the Šumava Mts. The knowledge of composition and chemistry of geological environment is very important for assessment of input and output of matter toúfrom this catchment. The geological underground has been make up of migmatitize biotitic and sillimaint-biotitic paragneises of Šumava Moldanubicum. Soils, represented by oligotrophic and oligomezotrophic cambisoils, are very acid, sorption unsaturated. Their silicate buffering system significantly contributes to decrease leaching of calcium, manganese, chlorine and total aluminium, and so to reduction of intensity weathering of rocks.